Fluorescent
Whitening Agents (also called optical brightener) absorb high energy radiation
in the ultraviolet to violet region (330nm-380nm) on the part of characteristic
molecules and emit lower energy radiation in blue region in visible spectrum
(400nm-450nm), which yields the counteracting the yellowing appearance. FWA
should be transparent on the substrate and should not absorb the visible region
of the spectrum. Many FWAs contain the structure of stilbene. Stilbene is an
unsaturated hydrocarbon with the formula C6H5CH=CHC6H5. Other nucleus of
FWAs are coumarin, imidazole, 1,3-diphenyl-2-pyrazolin, naphtalimid, benzoxazole
and heteroaromatics. FWAs are used in thermoplastics, detergents, plastic films,
fibers, papers, adhesives and leathers to enhance the appearance.